有机硅功能纳米复合材料科研团队

上传时间 :2019-05-18 13:33:04    浏览次数 :261    作者与来源 :苏丽

团队简介

本团队长期从事特种有机硅分子及其功能纳米复合材料基础与应用研究,主要研究方向:(i)特种功能有机(氟)硅分子的设计、合成与应用研究;(ii)高强/阻燃/导电/导热等有机硅功能复合材料及其智能传感器的设计与绿色制造;(iii)有机硅分子及其纳米复合材料的表界面调控及其结构-性能关系研究;(iv)多层级有机硅纳米复合材料的热-力耦合行为与协同机制研究;近年来主持/参与国家自然科学基金、浙江省重大科技专项、浙江省自然科学基金和企业横向项目等20多项,已在ACS Nano, Journal of Materials Chemistry A等杂志上发表论文60余篇,申请和授权国家发明专利30多项。

团队负责人: 汤龙程 (博士,研究员)  

团队成员: 张国栋(博士  高级实验师), 赵丽(博士  副研究员), 王华兰(博士  助理研究员), 龚丽秀(硕士  研究助理)


汤龙程团队合影

有机硅功能纳米复合材料科研团队

团队成员

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汤龙程(Long-Cheng Tang),博士,研究员,硕士生导师

长期从事功能有机硅分子及其高分子纳米复合材料的基础和应用研究;近年来围绕有机硅分子/纳米材料/有机分子间多相界面和多层级结构的绿色构筑,重点开展高强/阻燃/导电/导热等功能有机硅纳米复合材料的设计、性能调控与应用技术开发等。先后主持和参与了国家自然科学基金、浙江省重大科技专项、浙江省自然科学基金和企业横向项目等20多项。已在ACS Nano,Journal of Materials Chemistry A,Nanoscale,Carbon,Chemical Engineering Journal,Composites Science and Technology等期刊上发表学术论文50余篇,被引用2700多次;其中,1篇研究论文最高被引>500次,3篇研究论文被引>200次,5篇论文入选ISI-ESI高被引论文(前1%),2篇论文分别入选相应杂志最热门25篇论文,1篇获得2017年度Composites Part A杂志高被引论文奖。已申请国际专利和中国专利30多项,其中已授权20项,部分已在合作企业转化。先后入选“浙江省青年科学家培养计划”(2013),浙江省“151”人才工程(第三层次,2014),杭州市“131”中青年人才(第二层次,2017),获得2017年度Composites Part A杂志Editor’s Top Reviewer Award。

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张国栋(Guo-Dong Zhang),博士,高级实验师,硕士生导师

主要从事新型有机氟/硅材料及聚合物的制备、性能研究及其应用开发。先后主持和参与国家级项目3项,省级项目4项,校企合作项目7项。近年来在国内外学术期刊上发表SCI上论文10多篇,获授权国家发明专利6项。应用研究方向主要包括:特种氟硅聚合物与氟硅橡胶/氟硅硅油、轻质阻燃发泡硅胶、加成型硅凝胶、导热/导电硅橡胶、高透明弹性有机硅薄膜/涂层、超疏水有机硅涂层、有机硅剪切增稠液、有机硅乳液等,部分产品与技术已在合作企业转化。


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赵丽(Li Zhao),博士,副研究员,硕士生导师 

从事多相多组分聚合物复合材料的制备、功能特性、结构-性能-流变行为相关性研究,重点开展导电、电阻外场刺激敏感、疏水自清洁等功能氟硅复合材料与碳链高分子/有机硅高分子复合材料的基础和应用研究。先后主持国家、省自然科学基金、校企合作等项目等近10项。已在Nanoscale,Chemical Engineering Journal,Composites Science and Technology等国内外高分子材料领域重要期刊上发表SCI论文10余篇,获授权国家发明专利7项。


11

王华兰(Hua-Lan Wang),博士,助理研究员,硕士生导师

主要研究方向为有机/无机纳米杂化材料的结构/功能一体化设计及其在有机硅材料(硅橡胶)和储能领域(超级电容器、锂离子电池等)的应用。已主持国家自然科学基金、浙江省自然科学基金等项目多项,申请国家发明专利多项。已在ACS Applied Materials & Interfaces,Nanoscale,GreenChemistry等杂志上发表学术论文10多篇;其中,3篇研究论文入选ESI高被引论文。



团队研究领域 


QQ图片20190527171409


核心问题:如何实现多相界面和多层级结构的绿色可控构筑 

硅基新材料体系:结构/性能间构效关系及其机制机理研究 

        --为功能有机硅分子及其复合新材料的创制和开发奠定基础 


代表性成果 

发表SCI论文60余篇,被引用4000余次,单篇研究论文引用最高超500次; 

入选ESI高被引论文8篇,1篇获2017年Compos Part A高被引论文奖; 

开发了系列有机硅复合新材料和新技术,已授权国家发明专利30多项; 

2017年度Composites Part A Editor’s Top Reviewer Award。 


QQ图片20190527170834


部分应用项目


QQ图片20190528082930


主要科研项目

[22] 快速、高效电阻型火灾探测/预警传感器研发,杭州市科技发展计划项目,2019.1-2020.12,在研;

[21] 特种有机硅材料合成与产业化技术开发,企业合作项目,2019.1-2020.7,在研;

[20]高性能硅橡胶下游产品产业化开发,企业合作项目,2018.11-2020.7,在研;

[19] 硅烷化碳纤维@海绵材料的高效、持久油污染处理关键技术研究,杭州市科技发展计划项目,2018.1-2019.12,在研;

[18] 特种硅橡胶的合成与应用开发,企业合作项目,2017.11-2019.7,已结题;

[17] 绿色高效、低烟低毒有机硅阻燃材料,杭州市高层次留学回国人员(团队) 在杭创业创新项目, 2017.1-2018.12,已结题;

[16] 特种改性硅油的关键合成技术研发,企业合作项目,2017.1-2018.6,已结题;

[15] 三维石墨烯结构/聚合物纳米复合材料的控制制备及其力学可靠性研究,人社部科技活动项目择优资助, 2017.1-2017.12,已结题;

[14] 高效油水分离磁性超疏水海绵材料的制备关键技术研究, 浙江省公益技术计划项目, 2016.1-2017.12,已结题;

[13] 高性能有机硅塑料助剂研发技术服务,企业合作项目, 2016.11-2017.8,已结题;

[12] 有机硅复合阻燃技术的研发,企业合作项目,2016.12-2018.8,已结题;

[11] 100吨/年有机硅树脂微球的开发,企业合作项目,2016.1-2017.12,已结题;

[10] 新型低热膨胀系数高韧性环氧灌封胶研发,中国工程物理研究院电子工程研究所委托项目,2015.9-2017.2,已结题;

[9] 导电大分子功能化石墨烯构筑界面和形态结构可控的聚合物纳米复合材料及其力学行为研究,浙江省自然科学基金一般项目,2015.1-2017.12,已结题;

[8] 层状硅酸盐/导电粒子复配调控高分子复合材料电阻力场敏感性及其协同机理研究,国家自然科学基金青年基金项目,2015.1-2017.12,已结题;

[7]振荡力场作用下及作用后粒子填充高分子熔体的结构演化规律与机制研究, 浙江省自然科学基金青年科学基金项目,2014.1-2016.12,已结题;

[6] 双功能化石墨烯的可控制备及在硅橡胶中的应用,浙江省自然科学基金,项目负责人,2014.1-2016.12,已结题;

[5] 具有微纳孔结构的石墨烯/二氧化硅/PANI的跨纬度制备及电化学性能,国家自然科学基金青年科学基金项目,2014.1-2016.12,已结题;

[4] 加成型有机硅灌封胶的制备、结构和性能及其产业化技术的研发,浙江省重点企业研究院青年科学家培养计划项目,2014.1-2015.12,已结题;

[3] 多尺度纳米颗粒协同增韧热固性聚合物体系的构筑及其断裂机理研究,国家自然科学基金青年科学基金项目,2013.1-2015.12,已结题;

[2] 绿色环保脱醇型硅橡胶的性能调控及其应用产品研发,浙江省重大科技专项重点工业项目,2013.1-2015.12,已结题;

[1] 新型复合纳米体系硅树脂基阻燃防火材料的可控制备与性能调控研究,浙江省国际科技合作专项项目,2013.1-2015.12,已结题;


代表性论文著作(*通讯作者)

Chapters in books

[1]Long-Cheng Tang*, Li Zhao, Fei Qiang, Qian Wu, Li-Xiu Gong, Jin-Ping Peng. “Mechanical Properties of Rubber Nanocomposites Containing Carbon Nanofillers”, in Carbon-based nanofillers and their rubber nanocomposites, ed: S. Yaragalla, RK. Mishra, S Thomas, N Kalarikkal, HJ. Maria, Chapter 12, pp 367-423, 2019, Elsevier, Netherlands, ISBN 978-0-12-817342-8.

[2] Long-Cheng Tang*, Li Zhao, Li-Zhi Guan, “Graphene/Polymer Composite Materials: Processing, Properties and Applications”, in Advanced Composite Materials: Properties and Applications, ed: Ehsan Bafekrpour, Chapter 7, pp 349-419, 2017, DE GRUYTER, Germany, ISBN 978-3-11-057443-2.

Refereed journal papers

[33] Li Zhao#, Fei Qiang#, Shou-Wei Dai, Shi-Chang Shen, Yun-Zhuo Huang, Neng-Jian Huang, Guo-Dong Zhang, Li-Zhi Guan Jie-Feng Gao, Yihu Song, Long-Cheng Tang*. Construction of Sandwich-like Porous Structure of Graphene-Coated Foam Composites for Ultrasensitive and Flexible Pressure Sensor. Nanoscale, 2019, DOI: 10.1039/C9NR02672J.(JCR一区,工程技术类,IF=7.233)

[32] Junchen Luo, Ling Wang, Xuewu Huang, Bei Li, Zheng Guo, Xin Song, Liwei Lin, Long-Cheng Tang, Huaiguo Xue, Jiefeng Gao*. Mechanically Durable, Highly Conductive, and Anticorrosive Composite Fabrics with Excellent Self-Cleaning Performance for High-Efficiency Electromagnetic Interference Shielding. ACS Applied Materials & Interfaces, 2019, 11, 10883-10894.(JCR一区,工程技术类,IF=8.097)

[31] Neng-Jian Huang, Cheng-Fei Cao, Yang Li, Li Zhao, Guo-Dong Zhang, Jie-Feng Gao, Li-Zhi Guan, Jian-Xiong Jiang, Long-Cheng Tang*. Silane grafted graphene oxide papers for improved flame resistance and fast fire alarm response. Composites Part B, 2019, 168: 413-420.(JCR二区,工程技术类,IF=4.920)

[30] Jiefeng Gao*, Junchen Luo, Ling Wang, Xuewu Huang, Hao Wang, Xin Song, Mingjun Hu, Long-Cheng Tang, Huaiguo Xue. Flexible, superhydrophobic and highly conductive composite based on non-woven polypropylene fabric for electromagnetic interference shielding. Chemical Engineering Journal, 2019, 364,493-502. (JCR一区,工程技术类,IF=6.735)

[29] Fei Qiang, Shou-Wei Dai, Li Zhao*, Li-Xiu Gong, Guo-Dong Zhang, Jian-Xiong Jiang, Long-Cheng Tang*, An insulating second filler tuning porous conductive composites for highly sensitive and fast responsive organic vapor sensor. Sensors & Actuators: B. Chemical, 2019, 285: 254-263. (JCR一区,工程技术类,IF=5.667)

[28] Cheng-Fei Cao, Guo-Dong Zhang, Li Zhao, Li-Xiu Gong, Jie-Feng Gao, Jian-Xiong Jiang, Long-Cheng Tang*, Yiu-Wing Mai, Design of mechanically stable, electrically conductive and highly hydrophobic three-dimensional graphene nanoribbon composites by modulating the interconnected network on polymer foam skeleton. Composites Science and Technology, 2019, 171: 162-170. (JCR二区,工程技术类,IF=5.160)

[27] Shi-Neng Li, Baoqiang Li*, Li-Xiu Gong, Zhi-Ran Yu, Yujie Feng, Dechang Jia, Yu Zhou, Long-Cheng Tang*, Enhanced mechanical properties of polyacrylamide/chitosan hydrogels by tuning the molecular structure of hyperbranched polysiloxane. Materials and Design, 2019, 162: 162-170. (JCR二区,工程技术类,IF=4.525)

[26] Hui Xu, Yang Li, Neng-Jian Huang, Zhi-Ran Yu, Peng-Huan Wang, Zhao-Hui Zhang, Qiao-Qi Xia, Li-Xiu Gong, Shi-Neng Li, Li Zhao, Guo-Dong Zhang, Long-Cheng Tang*, Temperature-triggered sensitive resistance transition of graphene oxide wide-ribbons wrapped sponge for fire ultrafast detecting and early warning. Journal of Hazardous Materials, 2019, 363: 286-294. (JCR一区,工程技术类,IF=6.434)

[25] Ling Wang, Hao Wang, Xue-Wu Huang, Xin Song, Mingjun Hu, Long-Cheng Tang, Huaiguo Xue, Jiefeng Gao*. Superhydrophobic and superelastic conductive rubber composite for wearable strain sensors with ultrahigh sensitivity and excellent anti-corrosion property. J. Mater. Chem. A, 2018,6, 24523-24533. (JCR一区,工程技术类,IF=9.931)

[24] Li-Zhi Guan, Li Zhao, Yan-Jun Wan, Long-Cheng Tang*, Three-dimensional graphene-based polymer nanocomposites: preparation, properties and applications. Nanoscale, 2018, 10: 14788. (JCR一区,工程技术类,IF=7.233)

[23] Qian Wu, Li-Xiu Gong, Yang Li, Cheng-Fei Cao, Long-Cheng Tang*,Lianbin Wu, Li Zhao, Guo-Dong Zhang, Shi-Neng Li, Jiefeng Gao, Yongjin Li, and Yiu-Wing Mai*. Efficient Flame Detection and Early Warning Sensors on Combustible Materials Using Hierarchical Graphene Oxide/Silicone Coatings. ACS Nano, 2018, 12(1), 416-424. (JCR一区,工程技术类,IF=13.709)

[22] Fei Qiang, Li-Li Hu, Li-Xiu Gong, Li Zhao*, Shi-Neng Li, Long-Cheng Tang∗. Facile synthesis of super-hydrophobic, electrically conductive and mechanically flexible functionalized graphene nanoribbons/polyurethane sponge for efficient oil/water separation at static and dynamic states. Chemical Engineering Journal, 2018, 334, 2154-2166. (ESI Highly Cited Paper) (JCR一区,工程技术类,IF=6.735)

[21] Qian Wu, Qian Zhang, Li Zhao, Shi-Neng Li, Lian-Bin Wu∗, Jian-Xiong Jiang, Long-Cheng Tang∗. A novel and facile strategy for highly flame retardant polymer foam composite materials: Transforming silicone resin coating into silica self-extinguishing layer. Journal of Hazardous Materials, 2017, 336, 222-231.(JCR一区,工程技术类,IF=6.434)

[20] Jiefeng Gao*, Xuewu Huang, Huaiguo Xue, Long-Cheng Tang*, Robert K.Y. Li Facile preparation of hybrid microspheres for super-hydrophobic coating and oil-water separation. Chemical Engineering Journal, 2017, 326, 443-453. (ESI Highly Cited Paper) (JCR一区,工程技术类,IF=6.735)

[19] Neng-Jian Huang, Jing Zang, Guo-Dong Zhang*, Li-Zhi Guan, Shi-Neng Li, Li Zhao, Long-Cheng Tang∗. Efficient interfacial interaction for improving mechanical properties of polydimethylsiloxane nanocomposites filled with low content of graphene oxide nanoribbons. RSC Advances, 2017, 7, 22045-22053. (IF=3.108)

[18] Hui Xu, Li-Xiu Gong, Xu Wang, Li Zhao*, Yong-Bing Pei, Gang Wang*, Ya-Jun Liu, Lian-Bin Wu, Jian-Xiong Jiang, Long-Cheng Tang*. Influence of processing conditions on dispersion, electrical and mechanical properties of graphene-filled-silicone rubber composites. Composites: Part A, 2016, 91, 53-64.(JCR二区,工程技术类,IF=4.920)

[17] Li-Xiu Gong, Yong-Bing Pei*, Qing-Yu Han, Li Zhao, Lian-Bin Wu, Jian-Xiong Jiang, Long-Cheng Tang*. Polymer grafted reduced graphene oxide sheets for improving stress transfer in polymer composites. Composites Science and Technology, 2016, 134,144-152.(JCR二区,工程技术类,IF=5.160)

[16] Li-Zhi Guan, Jie-Feng Gao, Yong-Bing Pei, Li Zhao, Li-Xiu Gong, Yan-Jun Wan, Helezi Zhou, Nan Zheng, Xu-Sheng Du, Lian-Bin Wu, Jian-Xiong Jiang, Hong-Yuan Liu, Long-Cheng Tang*, Yiu-Wing Mai. Silane bonded graphene aerogels with tunable functionality and reversible compressibility. Carbon, 2016, 107, 573-582.(JCR一区,工程技术类,IF=7.082)

[15] Li-Xiu Gong, Li Zhao, Long-Cheng Tang*, Hong-Yuan Liu, Yiu-Wing Mai. Balanced electrical, thermal and mechanical properties of epoxy composites filled with chemically reduced graphene oxide and rubber nanoparticles. Composites Science and Technology, 2015, 121, 104-114.(JCR二区,工程技术类,IF=5.160)

[14] Jing Zang, Yan-Jun Wan, Li Zhao, Long-Cheng Tang*. Fracture Behaviors of TRGO-Filled Epoxy Nanocomposites with Different Dispersion/Interface Levels. Macromolecular Materials and Engineering, 2015, 300, 737-749.(JCR二区,工程技术类,IF=2.863)

[13] Xu Wang, Li-Xiu Gong, Long-Cheng Tang*, Ke Peng, Yong-Bing Pei, Li Zhao*, Lian-Bin Wu, Jian-Xiong Jian. Temperature dependence of creep and recovery behaviors of polymer composites filled with chemically reduced graphene oxide. Composites Part A, 2015, 69, 288-298.(JCR二区,工程技术类,IF=4.920)

[12] Li-Zhi Guan, Li-Xiu Gong, Long-Cheng Tang*, Lian-Bin Wu, Jian-Xiong Jiang, Guo-Qiao Lai. Mechanical properties and fracture behaviours of epoxy composites with phase-separation formed liquid rubber and preformed powdered rubber nanoparticles: A comparative study. Polymer Composites, 2015, 36(5), 785-799. (Featured articles from May's issue of Polymer Composites in 2015).(IF=1.943)

[11] Li-Zhi Guan, Yan-Jun Wan, Li-Xiu Gong, Dong Yan, Long-Cheng Tang*, Lian-Bin Wu, Jian-Xiong Jiang*, Guo-Qiao Lai. Toward effective and tunable interphases in graphene oxide/epoxy composites by grafting different chain lengths of polyetheramine onto graphene oxide. Journal of Materials Chemistry A, 2014, 2(36), 15058- 15069.(JCR一区,工程技术类,IF=9.931)

[10] Yan-Jun Wan, Li-Xiu Gong, Long-Cheng Tang*, Lian-Bin Wu, Jian-Xiong Jiang. Mechanical properties of epoxy composites filled with silane-functionalized graphene oxide. Composites Part A, 2014; 64, 79-89. (Top 25 Hottest Articles in Composites Part A, ESI Highly Cited Paper 2015-2017)(JCR二区,工程技术类,IF=4.920)

[9] Yan-Jun Wan, Long-Cheng Tang*, Li-Xiu Gong, Dong Yan, Yi-Bao Li, Lian-Bin Wu, Jian-Xiong Jiang, Guo-Qiao Lai. Grafting of epoxy chains onto graphene oxide for epoxy composites with improved mechanical and thermal properties. Carbon, 2014, 69, 467-480. (ESI Highly Cited Paper 2014-2017) (JCR一区,工程技术类,IF=7.082)

[8] Long-Cheng Tang*, Xu Wang, Li-Xiu Gong, Ke Peng, Li Zhao*, Qiu Chen, Lian-Bin Wu*, Jian-Xiong Jiang, Guo-Qiao Lai. Creep and recovery of polystyrene composites filled with graphene additives. Composites Science and Technology, 2014, 91, 63-70.(JCR二区,工程技术类,IF=5.160)

[7] Long-Cheng Tang*, Yan-Jun Wan, Dong Yan, Yong-Bing Pei, Li Zhao, Yi-Bao Li, Lian-Bin Wu*, Jian-Xiong Jiang, Guo-Qiao Lai.The effect of graphene dispersion on the mechanical properties of graphene/epoxy composites. Carbon, 2013, 60, 16-27. (Top 25 Hottest Articles in Carbon, Highly Cited Paper 2014-2017) (JCR一区,工程技术类,IF=7.082)

[6] Yan-Jun Wan, Long-Cheng Tang*, Dong Yan, Li Zhao, Yi-Bao Li*, Lian-Bin Wu, Jian-Xiong Jiang, Guo-Qiao Lai. Improved dispersion and interface in the graphene/epoxy composites via a facile surfactant-assisted process. Composites Science and Technology, 2013, 82, 60-68.(JCR二区,工程技术类,IF=5.160)

[5] Long-Cheng Tang*, Xu Wang, Yan-Jun Wan, Lian-Bin Wu, Jian-Xiong Jiang, Guo-Qiao Lai*. Mechanical properties and fracture behaviors of epoxy composites with multi-scale rubber particles. Materials Chemistry and Physics, 2013, 141, 333-342.(JCR二区,工程技术类,IF=2.210)

[4] Long-Cheng Tang*, Yan-Jun Wan, Ke Peng, Yong-Bing Pei, Lian-Bin Wu, Li-Min Chen, Li-Jin Shu, Jian-Xiong Jiang, Guo-Qiao Lai*. Fracture toughness and electrical conductivity of epoxy composites filled with carbon nanotubes and spherical particles. Composites Part A, 2013, 45, 95-101. (JCR二区,工程技术类,IF=4.920)

[3] Long-Cheng Tang, Hui Zhang*, Stephan Sprenger, Lin Ye, Zhong Zhang*. Fracture mechanisms of epoxy-based ternary composites filled with rigid-soft particles. Composites Science and Technology, 2012, 72(5), 558-65. (JCR二区,工程技术类,IF=5.160)

[2] Long-Cheng Tang, Hui Zhang, Jin-hua Han, Xiao-ping Wu, Zhong Zhang*. Fracture mechanisms of epoxy filled with ozone functionalized multi-wall carbon nanotubes. Composites Science and Technology, 2011, 72(1), 7-13.(JCR二区,工程技术类,IF=5.160)

[1] Long-Cheng Tang, Hui Zhang, Xiao-ping Wu, Zhong Zhang*. A novel failure analysis of multi-walled carbon nanotubes in epoxy matrix. Polymer, 2011, 52(9), 2070-2074. (IF=3.483)


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电子邮箱:lctang@hznu.edu.cn或hnutlc@163.com

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