徐利文

苏丽
2016-05-04
80

 

 

徐利文照片-2014

 

 

姓名:徐利文

职称:研究员(博士生导师)

学历:博士(后)

电子信箱liwenxu@hznu.edu.cnlicpxulw@yahoo.com

出生年月19766

研究方向:有机化学、有机硅化学、均相与不对称催化

毕业学校:中国科学院兰州化学物理研究所

职务

个人简介:(包含个人学习/经历,研究方向及兴趣,主持/参与项目情况,学术成果情况,教学情况,获奖情况)

博士毕业后先后在中国科学院兰州化学物理研究所羰基合成与选择氧化国家重点实验室(副研究员,主任助理)、杭州师范大学有机硅化学及材料技术教育部重点实验室(研究员,科研团队负责人)从事研究工作,期间还先后在法国国家科研中心、新加坡国立大学及东京大学(JSPS学者)从事合作研究工作,近年来还先后被遴选为杭州市政府特殊津贴获得者,浙江省高校中青年学科带头人,杭师大校学术委员会委员,浙江省杰出青年基金获得者。目前主要从事不对称催化合成及有机硅化学、均相催化及有机硅新材料等方面的研究,先后主持了10余项省部级及以上各类科技项目,迄今已在Chem. Soc. Rev., Angew. Chem. Int. Ed.等化学类国际著名学术期刊发表论文150余篇,并已被引用超3000次(H因子为29);近年来已获得国内外科技成果奖励5项,包括2项省部级自然科学二等奖及1项德国的Thieme Chemistry Journal Award国际学术奖。

现为有机硅化学及材料技术教育部重点实验室副主任。

近5年来的代表性成果:

1. Xing-Feng Bai, Tao Song, Zheng Xu, Chun-Gu Xia, Wei-Sheng Huang, Li-Wen Xu*Aromatic Amide-derived Non-Biaryl Atropisomers As Highly Efficient Ligands in Silver-Catalyzed Asymmetric Cycloaddition Reactions, Angew. Chem. Int. Ed. 2015, 54, 5255-5259.

2. Li-Wen Xu*, Yun Chen, Yixin Lu, Catalytic Silylations of Alcohols: Turning Simple Protecting-Group Strategies into Powerful Enantioselective Synthetic Methods, Angew. Chem. Int. Ed., 2015, 54, 94569466.

3. Xing-Feng Bai, Zheng Xu, Chun-Gu Xia, Zhan-Jiang Zheng, and Li-Wen Xu*, Aromatic-Amide-derived Non-biaryl Atropisomer As Highly Efficient Ligand for Asymmetric Silver-Catalyzed [3+2] Cycloaddition, ACS Catalysis, 2015, 5, 6016-6020.

4. Zheng Xu, Li-Wen Xu*, Development of Ar-BINMOL-derived Atropisomeric Ligands with Matched Axial and sp3-Central Chirality for Catalytic Asymmetric Transformations, The Chemical Record, 2015, 15, 925-948.

5. Zheng Xu, Li-Wen Xu*, Catalytic Silylation of Arenes with Hydrosilanes: Environmentally Benign Evolution from Transition Metal-Catalyzed C-X Bond Cleavage to Transition-Metal-Free C-H Bond Activation, ChemSusChem, 2015, 8, 2176-2179.

6. Tao Song, Li Li, Wei Zhou, Zhan-Jiang Zheng, Yuan Deng, Zheng Xu, Li-Wen Xu*, Enantioselective Copper-Catalyzed Azide-Alkyne Click Cycloaddition to Desymmetrization of Maleimide-based Bis-alkynes, Chem. Eur. J. 2015, 21, 554-558.

7. Cheng Dong, Tao Song, Xing-Feng Bai, Yu-Ming Cui, Zheng Xu, and Li-Wen Xu*, Enantioselective Conjugate Addition of Cyanide to Chalcones Catalyzed by Magnesium-Py-BINMOL Complex, Catal. Sci. Tech., 2015, 5, 4755-4759.

8. Long-Sheng Zheng, Yun-Long Wei, Ke-Zhi Jiang, Yuan Deng, Zhan-Jiang Zheng, and Li-Wen Xu*, Enantioselective Fluorination of b-Ketoamides Catalyzed by Ar-BINMOL-derived Salan-Copper Complex, Adv. Synth. Catal., 2014, 356, 3769-3776.

9. Tao Song, Long-Sheng Zheng, Fei Ye, Wen-Hui Deng, Yun-Long Wei, Ke-Zhi Jiang, and Li-Wen Xu*, Modular Synthesis of Ar-BINMOL-Phos for Catalytic Asymmetric Alkynylation of Aromatic Aldehydes with Unexpected Reversal of Enantioselectivity, Adv. Synth. Catal. 2014, 356, 1708-1718.

10. Fei Ye, Zhan-Jiang Zheng, Li Li, Ke-Fang Yang, Chun-Gu Xia, and Li-Wen Xu*, Development of A Novel Multifunctional N,P-Ligand for Highly Enantioselective Palladium-Catalyzed Asymmetric Allylic Etherification of Alcohols and Silanols, Chem. Eur. J. 2013, 19, 15452-15457.

11. Xing-Feng Bai, Fei Ye, Long-Sheng Zheng, Guo-Qiao Lai, Chun-Gu Xia, and Li-Wen Xu *, Hydrosilane and Bismuth-accelerated Palladium Catalyzed Aerobic Oxidative Esterification of Benzylic Alcohols with Air, Chem. Commun. 2012, 48, 8592 - 8594.

12. Li-Wen Xu*, Transition Metal Complex-Catalyzed Desymmetrization: A Facile Protocol to Enantioselective Construction of Silicon-Stereogenic Silanes, Angew. Chem. Int. Ed. 2012, 51, 12932-12934.

13. Hua-Meng Yang, Li Li, Fei Li, Ke-Zhi Jiang, Jun-Yan Shang, Guo-Qiao Lai, and Li-Wen Xu*, Silicon-based Lewis Acid Assisted Cinchona Alkaloid Catalysis: Highly Enantioselective Aza-Michael Reaction under Solvent-Free Conditions, Org. Lett. 2011, 13, 6508-6511.

14. Guang Gao, Feng-Lei Gu, Jian-Xiong Jiang, Kezhi Jiang, Chun-Qi Sheng, Guo-Qiao Lai, Li-Wen Xu*, Neighboring Lithium-Assisted [1,2]-Wittig Rearrangement: Practical Access to Diarylmethanol-based 1,4-Diols and Optically Active BINOL-derivatives with Axial and sp3 Central Chirality. Chem. Eur. J. 2011, 17, 2698-2703.

15. Li-Wen Xu *, Li Li, Guo-Qiao Lai, and Jian-Xiong Jiang, The Recent Synthesis and Application of Silicon-Stereogenic Silanes: A Renewed and Significant Challenge in Asymmetric Synthesis, Chem. Soc. Rev. 2011, 40, 1777-1790.

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