实验室主任-邱化玉

佚名
2015-04-21
683

 

 

个人简介:邱化玉(Qiu, H.-Y.),男,1963年出生,博士,教授,博士研究生导师,浙江省高等学校特聘教授(钱江学者),浙江省“151”人才第一层次,山东省千名知名技术专家。1984年毕业于山东大学获理学学士学位;1987年在山东大学获理学硕士学位并留校工作;1992年考取山东大学化学学院物理化学专业的博士研究生,师从于中国科学院院士、著名理论化学家邓丛豪教授,1996年获理学博士学位,同年赴美国北达克他州立大学化学系做博士后研究工作;199410月破格晋升副教授,199811月破格晋升教授。20052月作为浙江省高等学校特聘教授受聘到杭州师范大学工作至今,主要从事有机硅化学、有机及高分子功能材料等方面的研究。曾获国家发明三等奖、山东省科技进步一等奖和二等奖等多项奖励。主持和参与国家八五九五科技攻关计划、国家“863”计划、国家自然科学基金、教育部优秀青年教师基金、山东省中青年科学家奖励基金、山东省自然科学基金、浙江省高等学校特聘教授(钱江学者)基金、浙江省科技计划重点项目等20多项科研课题的研究工作。已在Chem. Eur. J, Chem. Asian J., J. Phys.Chem., Organometallics等期刊发表学术论文200余篇,被SCIEIISTP收录的学术论文100余篇。申请发明专利30余项,已授权15项。

  话:0571-28867899

电子邮件:huayuqiu@163.com

 

【主要学历】

1980.09-1984.07 山东大学化学学院,本科生,获理学学士

1984.09-1987.07 山东大学化学学院,硕士生,获理学硕士

1992.09-1996.07 山东大学化学学院,博士生,获理学博士

【主要学术经历】

1996.09-1998.08 美国北达克他州立大学化学系,博士后

【主要学术成就、奖励及荣誉】

   获国家发明三等奖、山东省科技进步一等奖和二等奖等多项奖励。

【主要研究方向】

1. 有机硅化学

2. 有机及高分子功能材料

【主要科研项目及角色】

1. 低倍MW级聚光型(CPV)并网电站光伏电池用关键材料的研制国家863”重点项目56万元,2008.1-2011.12,项目负责人

2. Silole和亚硅基σ-π共轭聚合物的设计合成、结构与性能,国家自然科学基金,56万元,2010.1-2010.12,项目负责人

3. Silole和联三吡啶Zn()单元共轭金属聚合物的设计、合成及性能研究,国家自然科学基金,56万元,2011.1-2013.12,项目负责人

4. 有机硅化学若干基础问题的研究省高校特聘教授(钱江学者)基金56万元,2006.1-2008.12,项目负责人

5. 高性能有机硅树脂绿色合成技术开发研究省科技计划重点项目56万元,2007.10-2009.9,项目负责人

6. 高性能有机硅材料的研究及产业化省科技重大专项56万元,2007.6-2009.12,项目负责人

【代表性论著】

    1Xu Z., Jin J., Li, Z.-F., Qiu, H.-Y., Jiang, J.-X., Lai, G.-Q. and Kira, M. 2009. Remarkable Substituent Effects on the Activation Energy of Silylene Insertion into Silicon–Chlorine Bonds. Chem. Eur. J. 15, 8605-8612 (SCI收录,影响因子5.454).

2Yang C.-J., Chen, X., Qiu, H.-Y. (邱化玉通讯联系人), Zhuang, W.-C., Chai, Y.-C. and Hao, J.-C. 2006. Dissipative particle dynamics simulation of phase behavior of aerosol OT/water system. J. Phys. Chem. B 110, 21735–21740 (SCI收录,影响因子4.189).

    3Wan J.-H., Fang, W.-F., Li Z.-F., Xiao X.-Q., Xu Z., Deng Y., Zhang, L.-H., Jiang, J.-X., Qiu, H.-Y., Wu, L-B. and Lai, G.-Q. (来国桥通讯联系人) 2010. Novel Ladder π-Conjugated Materials-Sila-Pentathienoacenes: Synthesis, Structure, and Electronic Properties. Chem. Asian J. 5, 2290-2296. (SCI收录,影响因子4.197).

    4Wan J.-H., Mao L-Y., Li Y.-B., Li Z.-F., Qiu H.-Y., Wang C. and Lai G.-Q. (来国桥通讯联系人) 2010. Self-assembly of novel fluorescent silole derivatives into different supramolecular aggregates: fibre, liquid crystal and monolayer. Soft Matter. 6, 3195-3201 (SCI收录影响因子4.586).

5Jin, S.-W, Chen, W. Z. and Qiu, H.-Y. (邱化玉,通讯联系人). 2007. Syntheses and Structural Characterization of a One-Dimensional Chain, Two-Dimensional Noninterpenetrated Grid, and Three-Dimensional Polycatenane Coordination Polymers Assembled from Flexible Bidentate Imidazolyl Ligands. Cryst. Growth Des. 7, 2071-2079. (SCI收录,影响因子4.04).

    6Lu C.-X., Gu S.-J., Chen W.-Z., and Qiu, H.-Y. (邱化玉,通讯联系人). 2010. Platinum(II) complexes with polydentate N-heterocyclic carbenes: synthesis, structural characterization and hydrosilylation catalysis. Dalton Trans. 39, 4198-4204 (SCI收录影响因子3.58).

    7Lai G.-Q., Xu Z., Li Z.-F., Jiang J.-X., Kira M. and Qiu, H.-Y. (邱化玉,通讯联系人). 2009. Stereoelectronic substituent effects on silylene insertion into the Si-Cl bond. Organometallics 28, 3591–3593. (SCI收录,影响因子3.815).

    8Jing B., Chen X., Zhao, Y.-R., Wang X.-D., Cai J.-G. and Qiu H.-Y. (邱化玉). 2008. Ionic self-assembled organic nanobelts from the hexagonal phase complexes and their cyclodextrin inclusions. J. Phys. Chem. B 112, 7191-7195. (SCI收录,影响因子4.189).

    9Zhang G.-D., Chen X., Zhao Y.-R., Ma F.-M., Jing B. and Qiu H.-Y. 2008. Lyotropic liquid-crystalline phases formed by Pluronic P123 inethylammonium nitrate. J. Phys. Chem. B 112, 6578-6584 (SCI收录,影响因子4.189).

    10Zhang G.-D., Chen X., Zhao Y.-R., Xie Y.-Z. and Qiu H.-Y. 2007. Effects of alcohols and counterions on the phase behavior of 1-octyl-3-methylimidazolium chloride aqueous solution. J. Phys. Chem. B 111, 11708-11713. (SCI收录,影响因子4.189).

    11Jing B., Chen X., Wang X.-D., Zhao Y.-R. and Qiu H.-Y. 2008. Sol-gel-sol transition of gold nanoparticle-based supramolecular hydrogels induced by cyclodextrin inclusion. ChemPhysChem. 9, 249-252 (SCI收录,影响因子3.636).

    12Peng J.-J., Li J.-Y., Bai Y., Qiu H.-Y. (邱化玉通讯联系人)., Jiang K.-Z., Jiang J.-X. and Lai, G.-Q. 2008. Ionic liquid (molten salt): Thermoregulated catalyst support for catalytic hydrosilylation process. Catal. Commun. 9, 2236–2238 (SCI收录,影响因子2.791).

    13Zhou Y.-B., Zhang X.-M., Chen W.-Z. and Qiu, H.-Y. (邱化玉通讯联系人). 2008. Synthesis, structural characterization, and luminescence properties of multinuclear silver complexes of pyrazole-functionalized NHC ligands containing Ag-Ag and Ag-pi interactions. J. Organometal. Chem. 693, 205–215 (SCI收录,影响因子1.866).

    14Peng J.-J., Li J.-Y., Bai Y., Gao W.-H., Qiu H.-Y. (邱化玉通讯联系人), Wu H. Deng Y. and Lai, G.-Q. 2007. Rh(PPh3)3Cl/ionic liquid (molten salt) as a thermoregulated and recyclable catalytic system for hydrosilylation. J. Mol. Catal. A-Chem. 278, 97–101 (SCI收录,影响因子2.814).

15Li Z.-F., Cao X.-J., Lai G.-Q., Liu J.-H., Ni Y., Wu J.-R., Qiu H.-Y. (邱化玉通讯联系人). 2006. Controlled introduction of allylic group to chlorosilanes. J. Organometal. Chem. 691, 4740–4746 (SCI收录,影响因子1.866).

16Li Z.-F., Yang C.-J., Zheng H.-F., Qiu, H.-Y. and Lai, G.-Q. (来国桥通讯联系人). 2008. Selective mono- and di-allylation and allenylation of chlorosilanes using indium. J. Organometal. Chem. 693: 3771-3779. (SCI收录,影响因子1.866).

17Jiang K.-Z., Ni Y., Qiu H.-Y. (邱化玉通讯联系人), Li M.-J., Jiang, J.-X. and Lai G.-Q. 2006. Separation of the isomers of oligomethylphenylcyclosiloxanes and determination of their structures by capillary GC-MS. Chromatographia. 64, 689–694. (SCI收录,影响因子1.312).

18Lai G.-Q., Peng J.-J., Li J.-Y., Qiu H.-Y., Jiang J.-X., Jiang K.-Z., Shen, Y.-J. 2006. Ionic liquid functionalized silica gel: novel catalyst and fixed solvent. Tetrahedron Lett. 47, 6951–6953 (SCI收录,影响因子2.538).

19Ju Y.-D., Xu L.W., Li L., Lai G.-Q. (来国桥通讯联系人)., Qiu H.-Y., Jiang J.-X., Lu Y.-X. 2008. Noyori’s Ts-DPEN ligand: an efficient bifunctional primary amine-based organocatalyst in enantio-and diastereoselective Michael addition of 1,3-dicarbonyl indane compounds to nitroolefins. Tetrahedron Lett. 49, 6773-6777.(Highlighted by SYNFACTS,2008,1328) (SCI收录,影响因子2.538).

20Peng J.-J., Li J.-Y., Bai Y., Gao W.-H., Qiu H.-Y., Wu H., Deng Y. and Lai G.-Q. (来国桥通讯联系人). 2007. Rh(PPh3)3Cl/ionic liquid (molten salt) as a thermoregulated and recyclable catalytic system for hydrosilylation. J. Mol. Catal. A-Chem. 278, 97-101 (SCI收录,影响因子2.814).

21Xu L.-W., Yang M.-S., Qiu H.-Y. (邱化玉,通讯联系人)., Lai G.-Q. (来国桥,通讯联系人) and Jiang J.-X. 2008. Efficient iron-catalyzed Sakurai-Michael addition of allyltrimethylsilane to chalcones. Synthetic Commun. 38, 1011-1019 (SCI收录,影响因子0.981).

22Yang M.-S., Xu L.-W., Qiu H.-Y. (邱化玉,通讯联系人), Lai, G.-Q. (来国桥,通讯联系人) and Jian;g, J.-X. 2008. Highly efficient indium-catalyzed chemo- selective allylation-etherification and reductive etherification of aromatic aldehydes with functional silanes. Tetrahedron. Lett. 49, 253-256 (SCI收录,影响因子2.538).

23Yang M.-S., Xu L.-W., Zhang F.-B., Qiu, H.-Y. (邱化玉,通讯联系人), Jiang J.-X. and Lai, G.-Q. (来国桥,通讯联系人). 2008. Highly efficient iron-catalyzed allylation of aromatic aldehydes with allyltriethoxysilane: one-pot and practical synthesis of homoallyl ethers. Appl. Organomet. Chem. 22, 177-180. (SCI收录,影响因子1.27).

24Chen C., Qiu H.-Y. (邱化玉,通讯联系人), Chen W.-Z. and Wang D.-Q. 2008. Synthesis, structural characterization, and luminescence properties of multinuclear silver complexes of pyrazole-functionalized NHC ligands containing Ag-Ag and Ag-pi interactions. J. Organometal. Chem. 693, 205- 215 (SCI收录,影响因子1.866).

【授权专利】

1.     ZL200710069547.7一种细旦或超细旦尼龙纤维及其生产方法邱化玉,徐怡庄,来国桥,徐利文,吴燕婕,章成峰,刘毓海,李志芳

2.     ZL200610048928.2一种异硫氰酸酯的合成方法边高峰,来国桥,邱化玉,胡自强,齐帆

3.     ZL200510061322.8有机聚硅烷的制备方法李志芳,来国桥,邱化玉,毛建江,盛春荠

4.     ZL200610050555.2李志芳,来国桥,邱化玉,蒋可志,曹肖君,烯丙基氯硅烷的制备方法。

5.     ZL200710068597.3一种硅氢加成反应担载型双金属催化剂及制备方法,白赢,彭家建,厉嘉云,邱化玉,徐利文,李文清,罗蒙贤。

6.     ZL200710067240.3,一种金属卟啉/二氧化硅降解剂的制备方法,吕素芳,李美江,伍川,蒋可志,邱化玉,陈利民。

7.     ZL200510061318.1, 一种采用新型离子液体聚合引发体系制备高分子化合物的方法,胡自强,来国桥,彭家建,邱化玉,蒋可志,祝根平。

8.     ZL200610050813.7,一种34'-二氨基二苯醚的制备及分离提纯方法,伍川,邱化玉,蒋可志,吴连斌,李文清。

9.     ZL200610172229.9,超临界状态下的原子转移自由基聚合引发体系,来国桥,陈利民,蒋剑雄;邱化玉,罗蒙贤。

10. ZL200610048929.7,一种反向ATRP引发体系及其在制备高分子化合物的应用,胡自强,来国桥,邱化玉,吴连斌,邬继荣。

11. ZL200510061321.3多官能基硅化合物的制备李美江,来国桥,蒋剑雄,邱化玉,潘庆华。

12. ZL200510061322.8,两步法化学提纯甲基苯基二氯硅烷的方法,李志芳,来国桥,邱化玉,毛建江,盛春荠。

13. ZL200710068595.4,一种羟基封端聚甲基苯基硅氧烷的制备方法,李美江,蒋剑雄,吕素芳,邱化玉,邓元。

14. ZL200710070023.X,一种侧链含四硫代富瓦烯结构单元的聚硅烷制备方法,李美江,吕素芳,来国桥,邱化玉,蒋剑雄。

15. ZL200510061319.6含稠环基聚硅烷制备方法,来国桥,李美江,李志芳,吕素芳,邱化玉,刘勇

 

 

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